MATERIAL SAFETY DATA SHEET
Revision Date: 09/29/2004
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SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT: Shell™ Hydraulic Oil 46
MSDS NUMBER: 60170E - 3
PRODUCT CODE(S): 65237, 6523700055
MANUFACTURER ADDRESS:SOPUS Products, P.O. Box 4427, Houston, TX. 77210-4427
TELEPHONE NUMBERS
Spill Information: (877) 242-7400
Health Information: (877) 504-9351
MSDS Assistance Number: (877) 276-7285
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SECTION 2 PRODUCT/INGREDIENTS
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CAS# CONCENTRATION INGREDIENTS
Hydraulic Oil
Blend 90 - 98.99 %weight Highly refined petroleum oils
Mixture 1 - 2.99 %weight Additives
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SECTION 3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
Appearance & Odor: Amber, clear liquid. Mild odor.
Health Hazards: No known immediate health hazards. High-pressure injection
under the skin may cause serious damage.
Physical Hazards: No known physical hazards.
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
Hazard Rating:Least - 0 Slight - 1 Moderate - 2 High - 3
Extreme - 4
Inhalation:
Inhalation of vapors (generated at high temperatures only) or oil mist may
cause mild irritation of the nose, throat, and respiratory tract.
Eye Irritation:
Lubricating oils are generally considered no more than minimally irritating to
the eyes.
Skin Contact:
May cause slight irritation of the skin. If irritation occurs, a temporary
burning sensation and minor redness and/or swelling may result. Release of
the material during high-pressure applications may result in injection under
the skin causing possible extensive tissue damage which is difficult to heal.
Other adverse effects not expected from brief skin contact.
Ingestion:
Lubricating oils are generally no more than slightly toxic if swallowed.
Signs and Symptoms:
Irritation as noted above. Local necrosis is evidenced by delayed onset of
pain and tissue damage a few hours following injection.
Aggravated Medical Conditions:
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure
to this product.
For additional health information, refer to section 11.
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SECTION 4 FIRST AID MEASURES
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Inhalation:
If the victim has difficulty breathing or tightness of the chest, is dizzy,
vomiting or unresponsive, give 100% oxygen with rescue breathing or CPR as
required and transport to the nearest medical facility.
Skin:
Remove contaminated clothing and shoes and wipe excess from skin. Flush skin
with water, then wash with soap and water. If irritation occurs, get medical
attention. Do not reuse clothing until cleaned. If material is injected
under the skin, transport to the nearest medical facility for additional
treatment. If redness, swelling, pain and/or blisters occur, transport to the
nearest medical facility for additional treatment.
Eye:
Flush with water. If irritation occurs, get medical attention.
Ingestion:
Do not induce vomiting. In general, no treatment is necessary unless large
quantities of product are ingested. However, get medical attention. Have
victim rinse mouth out with water, then drink sips of water to remove taste
from mouth. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration.
Note to Physician:
In general, emesis induction is unnecessary in high viscosity, low volatility
products such as oils and greases.
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SECTION 5 FIRE FIGHTING MEASURES
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Flash Point [Method]: 400 ºF -440 ºF/204.44 ºC -226.67 ºC [ Cleveland Open
Cup]
Extinguishing Media:
Material will float and can be re-ignited on surface of water.
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SECTION 6 ACCIDENTAL RELEASE MEASURES
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Protective Measures:
May burn although not readily ignitable.
Wear appropriate personal protective equipment when cleaning up spills. Refer
to Section 8.
Spill Management:
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or
other suitable material. Place in non-leaking container and seal tightly for
proper disposal.
Reporting:
CERCLA: Product is covered by EPA's Comprehensive Environmental Response,
Compensation and Liability Act (CERCLA) petroleum exclusion. Releases to air,
land, or water are not reportable under CERCLA (Superfund).
CWA: This product is an oil as defined under Section 311 of EPA's Clean Water
Act (CWA). Spills into or leading to surface waters that cause a sheen must be
reported to the National Response Center, 1-800-424-8802.
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SECTION 7 HANDLING AND STORAGE
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Precautionary Measures:
Wash with soap and water before eating, drinking, smoking, applying cosmetics,
or using toilet. Launder contaminated clothing before reuse. Properly
dispose of contaminated leather articles such as shoes or belts that cannot be
decontaminated. Avoid heat, open flames, including pilot lights, and strong
oxidizing agents. Use explosion-proof ventilation to prevent vapor
accumulation. Ground all handling equipment to prevent sparking.
Storage:
Do not store in open or unlabeled containers. Store in a cool, dry place with
adequate ventilation. Keep away from open flames and high temperatures.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been
emptied, can contain explosive vapors. Do not cut, drill, grind, weld or
perform similar operations on or near containers.
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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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Oil mist, mineral ACGIH TLV TWA: 5 mg/m3 STEL: 10 mg/m3
Oil mist, mineral OSHA PEL TWA: 5 mg/m3
EXPOSURE CONTROLS
Provide adequate ventilation to control airborne concentrations below the
exposure guidelines/limits.
PERSONAL PROTECTION
Personal protective equipment (PPE) selections vary based on potential
exposure conditions such as handling practices, concentration and ventilation.
Information on the selection of eye, skin and respiratory protection for use
with this material is provided below.
Eye Protection:
Chemical Goggles, or Safety Glasses
Skin Protection:
Use protective clothing which is chemically resistant to this material.
Selection of protective clothing depends on potential exposure conditions and
may include gloves, boots, suits and other items. The selection(s) should
take into account such factors as job task, type of exposure and durability
requirements.
Published literature, test data and/or glove and clothing manufacturers
indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level
which is adequate to protect worker health, an approved respirator must be
worn. Respirator selection, use and maintenance should be in accordance with
the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
For Mist: Air Purifying, R or P style NIOSH approved respirator.
For Vapors: Air Purifying, R or P style prefilter & organic cartridge,
NIOSH approved respirator. Self-contained breathing apparatus for use in
environments with unknown concentrations or emergency situations.
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
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Appearance & Odor: Amber, clear liquid. Mild odor.
Substance Chemical Family: Lubricants
API Gravity: 30 - 32.3
Appearance: Amber, clear liquid.
Flash Point: 400 ºF - 440 ºF [Cleveland Open Cup]
Pour Point: -10 ºF - 0 ºF
Specific Gravity: 0.8856
Viscosity: 30 cSt - 100 cSt @ 40 ºC
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SECTION 10 REACTIVITY AND STABILITY
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Stability:
Material is stable under normal conditions.
Conditions to Avoid:
Avoid heat and open flames.
Materials to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions.
A complex mixture of airborne solids, liquids and gases will evolve when this
material undergoes pyrolysis or combustion. Aldehydes, Carbon Monoxide,
Carbon Dioxide, Ketones, Methacrylate monomers
and other unidentified organic compounds may be formed upon combustion.
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SECTION 11 TOXICOLOGICAL INFORMATION
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Acute Toxicity
Dermal LD50 >5.0 g/kg(Rabbit) OSHA: Non-Toxic Based on components(s)
Oral LD50 >5.0 g/kg(Rat) OSHA: Non-Toxic Based on components(s)
Carcinogenicity Classification
Hydraulic Oil
NTP: No IARC: Not Reviewed ACGIH: No OSHA: No
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SECTION 12 ECOLOGICAL INFORMATION
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Environmental Impact Summary:
There is no ecological data available for this product. However, this product
is an oil. It is persistent and does not readily biodegrade. However, it
does not bioaccumulate.
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SECTION 13 DISPOSAL CONSIDERATIONS
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RCRA Information:
Under RCRA, it is the responsibility of the user of the material to determine,
at the time of the disposal, whether the material meets RCRA criteria for
hazardous waste. This is because material uses, transformations, mixtures,
processes, etc. may affect the classification. Refer to the latest EPA, state
and local regulations regarding proper disposal.
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SECTION 14 TRANSPORT INFORMATION
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US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or
highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
International Air Transport Association
Not regulated under IATA rules.
International Maritime Organization Classification
Not regulated under International Maritime Organization rules.
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SECTION 15 REGULATORY INFORMATION
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FEDERAL REGULATORY STATUS
OSHA Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29
CFR 1910.1200, because it carries the occupational exposure limit for mineral
oil mist.
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class
I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health:NO Delayed Health:NO Fire:NO Pressure:NO
Reactivity:NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
All component(s) of this material is(are) listed on the EPA/TSCA Inventory of
Chemical Substances.
Other Chemical Inventories:
Component(s) of this material is (are) listed on the Australian AICS,
Canadian DSL, Chinese Inventory, European EINECS, Korean Inventory,
Philippines PICCS,
State Regulation
The following chemicals are specifically listed by individual states; other
product specific health and safety data in other sections of the MSDS may also
be applicable for state requirements. For details on your regulatory
requirements you should contact the appropriate agency in your state.
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SECTION 16 OTHER INFORMATION
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Revision#: 3
Revision Date: 09/29/2004
Revisions since last change (discussion): This Material Safety Data Sheet
(MSDS) has been reviewed to fully comply with the guidance contained in the
ANSI MSDS standard (ANSI Z400.1-1998). We encourage you to take the
opportunity to read the MSDS and review the information contained therein.
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SECTION 17 LABEL INFORMATION
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READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF
PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL
IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND
MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR
OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODE(S): 65237, 6523700055
Shell™ Hydraulic Oil 46
ATTENTION!
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE OIL ACNE OR DERMATITIS.
HIGH-PRESSURE INJECTION UNDER SKIN MAY CAUSE SERIOUS DAMAGE.
Precautionary Measures:
Avoid prolonged or repeated contact with eyes, skin and clothing. Avoid
breathing of vapors, fumes, or mist. Use only with adequate ventilation.
Wash thoroughly after handling.
FIRST AID
Inhalation: If the victim has difficulty breathing or tightness of the chest,
is dizzy, vomiting or unresponsive, give 100% oxygen with rescue breathing or
CPR as required and transport to the nearest medical facility.
Skin Contact: Remove contaminated clothing and shoes and wipe excess from
skin. Flush skin with water, then wash with soap and water. If irritation
occurs, get medical attention. Do not reuse clothing until cleaned. If
material is injected under the skin, transport to the nearest medical facility
for additional treatment. If redness, swelling, pain and/or blisters occur,
transport to the nearest medical facility for additional treatment.
Eye Contact: Flush with water. If irritation occurs, get medical attention.
Ingestion: Do not induce vomiting. In general, no treatment is necessary
unless large quantities of product are ingested. However, get medical
attention. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration. Have victim rinse mouth out with water, then drink sips of water
to remove taste from mouth.
FIRE
In case of fire, Material will float and can be re-ignited on surface of
water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or
other suitable material. Place in non-leaking container and seal tightly for
proper disposal.
CONTAINS: Highly refined petroleum oils, Blend; Additives, Mixture
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
TRANSPORTATION
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or
highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
CAUTION: Misuse of empty containers can be hazardous. Empty containers can
be hazardous if used to store toxic, flammable, or reactive materials.
Cutting or welding of empty containers might cause fire, explosion or toxic
fumes from residues. Do not pressurize or expose to open flames or heat.
Keep container closed and drum bungs in place.
Name and Address
SOPUS Products
P.O. Box 4427
Houston, TX 77210-4427
ADMINISTRATIVE INFORMATION
MANUFACTURER ADDRESS: SOPUS Products, P.O. Box 4427, Houston, TX.
77210-4427
Company Product Stewardship & Regulatory Compliance Contact: Timothy W Childs
Phone Number: (713) 241-1524
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO
US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN.
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR
DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT
TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE
RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE
UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA,
IS THE PROPERTY OF SOPUS PRODUCTS AND IS NOT TO BE THE SUBJECT OF SALE OR
EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SOPUS PRODUCTS.
43309-11719-100R-09/29/2004